23. Mechanochemical Solvent-Free Catalytic C–H Methylation

Shengjun Ni, Matic Hribersek, Swarna Baddigam, Fredric L. J. Ingner, Andreas Orthaber, Paul J. GatesLukasz T. Pilarski*
Angew. Chem. Int. Ed. 2020. DOI: 10.1002/anie.202010202 | Selected as a 🔥 HOT PAPER 🔥|
† Equal contributions.

22. Mechanochemical Synthesis of (Hetero)Aryl Au(I) Complexes

Fredric L. J. Ingner, Zachary X. Giustra, Sebastian Novosedlik, Andreas Orthaber, Paul J. Gates, Christine Dyrager and Lukasz T. Pilarski*
Green Chem. 2020, 22, 5648-5655 [ Abstract | PDF ]    | Selected as a 🔥 2020 HOT Green Chemistry article 🔥|

21. Mild and Efficient Synthesis of Diverse Organo-Au(I)-L Complexes in Green Solvents

Fredric L. J. Ingner, Ann-Cathrin Schmitt, Andreas Orthaber, Paul J. Gates, Lukasz T. Pilarski*
ChemSusChem 202021, 2032-2037 [ Web pagePDF ]

Check out our article’s cover feature:

20. Arynes and Their Precursors from Arylboronic Acids via Catalytic C-H Silylation

Karthik Devaraj, Fredric L. J. Ingner, Carina Sollert, Paul J. Gates, Andreas Orthaber, Lukasz T. Pilarski*
J. Org. Chem. 2019, 84, 5863-5871 [ Web page | PDF ]   | ☝️ Selected for ACS Editor’s Choice |

19. Weinreb Amides as Directing Groups for Transition Metal-Catalyzed C-H Functionalization

Jagadeesh Kalepu, Lukasz T. Pilarski*
Molecules 2019, 24, 830 [ Web page | PDF ] | Invited contribution |

18. C4-H Indole Functionalisation: Precedent and Prospects

Jagadeesh Kalepu, Gandeepan Parthasarathy, Lutz Ackermann,* Lukasz T. Pilarski*
Chem. Sci. 2018, 9, 4203-4216 [ Web page | PDF ]

17. Young Career Focus: Interview with Lukasz Pilarski

Lukasz T. Pilarski*
Synlett 2017, 28, A83-A85 [ Web page | PDF ]
Invited contribution.

16. Ru-Catalysed C-H Silylation of Gramines, Tryptamines and their Congeners

Karthik Devaraj, Carina Sollert, Carmen Juds, Paul J. Gates, Lukasz T. Pilarski*
Chem. Commun. 2016, 52, 5868-5871 [ Web page | PDF ]

15. Selective Activation of Arylboronate or Aryne Reactivity as a Versatile Postfunctionalization Strategy

Johanna Larsson, Emilien Demory, Karthik Devaraj, Carina Sollert, Lukasz T. Pilarski*
Synlett 2016, 27 (7), 969-976 [ Web page | PDF ]

Invited contribution to SynPacts

14. Boryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis through C-H Activation and Orthogonal Reactivity

Emilien Demory, Karthik Devaraj, Andreas Orthaber, Paul J. Gates, Lukasz T. Pilarski*
Angew. Chem. 2015, 127, 11931–11935 [ PDF ] Angew. Chem. Int. Ed. 2015, 54, 11765–11769 [ Abstract | PDF ]

13. Crystal structure of aceto­nitrile­[η6-1-methyl-4-(1-methyl­eth­yl)benzene][1-(pyrimidin-2-yl)-3H-indol-1-ium-2-yl-κ2 N,C]ruthenium(II) bis­­(hexa­fluorido­anti­monate)

Carina Sollert, Andreas Orthaber*, Lukasz T. Pilarski*
Acta Cryst. 2015 E71, 1190-1192 [ Abstract | PDF ]

12. Ru-Catalysed C-H Arylation of Indoles and Pyrroles with Boronic Acids: Scope and Mechanistic Studies

Carina Sollert, Karthik Devaraj, Andreas Orthaber, Paul J. Gates, Lukasz T. Pilarski*
Chem. Eur. J. 2015 21, 5380–5386 [ Abstract | PDF ] | Selected as a 🔥 HOT PAPER 🔥|

Papers from Lukasz’s Postdoc

11. “Pincer Complexes in Catalysis”
L. T. Pilarski, K. J. Szabó* in Applied Homogeneous Catalysis with Organometallic Compounds
(Cornils, Herrmann, Paciello & Beller eds., Wiley-VCH, 2017).

ISBN-13: 978-3527328970
ISBN-10: 3527328971

10. Stereoselective Intermolecular Allylic C-H Trifluoroacetoxylation of Functionalized Alkenes
R. Alam, L. T. Pilarski, E. Pershagen, K. J. Szabó*
J. Am. Chem. Soc. 2012,134, 8778–8781.

9. Palladium Pincer Complex-Catalyzed Functionalization of Electrophiles
L. T. Pilarski, K. J. Szabó*
Curr. Org. Chem. 201115, 3389-3414

8. Palladium-catalyzed Direct Synthesis of Organoboronic Acids
L. T. Pilarski, K. J. Szabó*
Angew. Chem. 2011123, 8380–8382
Angew. Chem. Int. Ed. 201150, 8230-8232

7. “Palladium-Catalyzed Selective Acyloxylation Using Sodium Perborate as Oxidant
L. T. Pilarski, P. G. Janson, K. J. Szabó*
J. Org. Chem. 201176, 1503-1506

6.Diphenyliodonium hexafluorophosphate
L. T. Pilarski, K. J. Szabó*
Electronic Encyclopedia of Reagents for Organic Synthesis (Wiley, 2011). Eds: L. A. Paquette, P. Fuchs, D. Crich, G. A. Molander. Posted online September 2011.

5. Catalytic Allylic C-H Acetoxylation and Benzoyloxylation via Suggested (η3-Allyl)palladium(IV) Intermediates
L. T. Pilarski, N. Selander, D. Böse, K. J. Szabó*
Org. Lett. 200911, 5518-5521

Papers from Lukasz’s PhD

4.Chiral triaryl phosphite-based palladacycles and platinacycles: synthesis and application to asymmetric Lewis acid catalysis
R. B. Bedford,* H. Dumycz, M. F. Haddow, L. T. Pilarski, A. G. Orpen, P. G. Pringle, R. L. Wingad*
Dalton Trans. 200937, 7796-7804

3.Palladacyclic and platinacyclic catalysts for the allylation of aldehydes
R. B. Bedford*, L. T. Pilarski
Tetrahedron Lett. 200849, 4216-4219

2.Simple palladacyclic and platinacyclic catalysts for the 1,4-conjugate addition of arylboronic acids and arylsiloxanes to enones
R. B. Bedford,* M. Betham, J. P. H. Charmant, M. F. Haddow, A. G. Orpen and L.T. Pilarski
Organometallics 200726, 6346-6353

1.Chiral palladium bis(phosphite) PCP-pincer complexes via ligand C-H activation
R. A. Baber, R. B. Bedford,* M. Betham, M. E. Blake, S. J. Coles, M. F. Haddow, M. B. Hursthouse, A. G. Orpen, L. T. Pilarski, P. G. Pringle,* R. L. Wingad
Chem. Commun. 2006, 3880-3882

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